Skip to content
ENExplore Calculators

Empirical Formula Calculator

Derive the simplest whole-number formula from percentage composition.

About Empirical Formula Calculator

Assuming a 100 g sample turns mass percentages into grams directly. Dividing by atomic masses gives moles, and normalising by the smallest gives the atom ratio — 1:2:1 for glucose, hence CH₂O. The empirical formula is a ratio only; the molecular formula is a whole-number multiple of it, which requires the molar mass to determine.

Formula

Empirical Formula

Divide each mass percent by its atomic mass, then divide all results by the smallest

empirical formula
Simplest whole-number ratio of atoms, which may not be the molecular formula

Worked example

With the default values below, Empirical Formula Calculator returns Relative Atoms of Element 1 of 1.0000. Change any input above and every figure here is recalculated in your browser.

Inputs used

Mass percent of element 1accepts 0–100 %
40 %
Atomic mass of element 1minimum 0 g/mol
12.011 g/mol
Mass percent of element 2accepts 0–100 %
6.7 %
Atomic mass of element 2minimum 0 g/mol
1.008 g/mol
Mass percent of element 3accepts 0–100 %
53.3 %
Atomic mass of element 3minimum 0 g/mol
15.999 g/mol

Results

Relative Atoms of Element 1
1.0000
Relative Atoms of Element 2
1.9959
Relative Atoms of Element 3
1.0004
Empirical Formula Mass
30.0275 g/mol
Smallest Mole Value Used to Normalise
3.330281

Step by step

  1. 1Values used
  2. 2Empirical Formula
  3. 3Relative Atoms of Element 1= 1.0000
  4. 4Relative Atoms of Element 2= 1.9959
  5. 5Relative Atoms of Element 3= 1.0004
  6. 6Empirical Formula Mass= 30.0275 g/mol
  7. 7Smallest Mole Value Used to Normalise= 3.330281

Assumptions and limits

  • The result is derived only from the 6 inputs listed above. Anything not among them is not part of the calculation.
  • In particular, this calculator does not take inflation, tax, fees or charges or compounding frequency into account.
  • Figures are rounded for display to 6 decimal places, so totals built from several rounded parts can differ slightly from the unrounded arithmetic.

How these calculators are built and tested is described on the Methodology page. If a figure looks wrong, please report it.

Frequently Asked Questions

How is Empirical Formula calculated?

Divide each mass percent by its atomic mass, then divide all results by the smallest Assuming a 100 g sample turns mass percentages into grams directly. Dividing by atomic masses gives moles, and normalising by the smallest gives the atom ratio — 1:2:1 for glucose, hence CH₂O.

Why does Empirical Formula matter?

The empirical formula is a ratio only; the molecular formula is a whole-number multiple of it, which requires the molar mass to determine.

What values do I need to enter?

This calculator takes 6 inputs: Mass percent of element 1, Atomic mass of element 1, Mass percent of element 2, Atomic mass of element 2, Mass percent of element 3, Atomic mass of element 3. The pre-filled defaults are a realistic starting point — replace them with figures from your own environment for a result you can act on.

Empirical Formula Calculator | Calcrivo